It is often found in the plates/electrodes of car batteries because it is formed when the battery is discharged (when the battery is charged, the lead sulfate is converted back to metallic lead and sulfuric acid or lead dioxide and the positive terminal on the negative terminal sulfuric acid). Lead sulfate is insoluble in water. Hornstone (lead(II) sulfate, PbSO4) adopts the same orthorhombic crystal structure as celestite (strontium sulfate, SrSO4) and barite (barium sulfate, BaSO4). The structures of all three minerals are in the space group Pbnm (number 62). [6] Each lead(II) ion is surrounded by 12 oxygen atoms from 7 sulfate ions, forming a PbO12 polyhedron. [7] The lead-oxygen distance ranges from 2.612 Å to 3.267 Å, with an average distance of 2.865 Å.
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