What is Valium? Valium is a benzodiazepine (ben-zoe-dye-AZE-eh-peen). It is thought that diazepam works by enhancing the activity of certain neurotransmitters in the brain. Valium is used to treat anxiety disorders, or alcohol withdrawal symptoms. Valium is sometimes used with other medications to treat muscle spasms and stiffness, or seizures.
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