Reminiscent of Berthelot's experiments, glycerol to epichlorohydrin (GTE) plants have been commercialized. The technology takes advantage of the availability of cheap glycerol in biofuel processing. [9] In a process developed by Dow Chemical, two substitution reactions occur when glycerol is treated with hydrogen chloride in the presence of a carboxylic acid catalyst. This is the same intermediate formed in the allyl chloride/hypochlorous acid process, which is then likewise treated with base to form epichlorohydrin.
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