Fumigants serve agriculture’s storage systems, field operations, horticultural processes, and pest mitigation missions. Included substances: chloroacetone, formamide, dibutyl phthalate, hydrazine, and trisodium phosphate. Systems applied involve hand-held blasters, environmental chambers, vent lock units, gauging rigs, fumigant timers, and remote alerting devices. Ecosystem includes tech advisors, rural health officers, import-export analysts, shipping crews, fumigant specialists, and sustainability mentors. Benefits achieved are crop cleanliness, trade facilitation, biological neutrality, infestation restraint, and operational readiness. Roadblocks include climate variation, user errors, legal barriers, and community discomfort. Breakthroughs include precision air routing, green compound deployment, digital safety tracking, and policy-driven labeling improvements.